In the past, some episodes were released on DVD by Shemaroo or other distributors. You may find these on secondary markets, but OTT is far more practical.
If you truly want to watch Chakravartin Ashoka Samrat start to finish, follow this guide: chakravartin ashoka samrat all episodes - youtube
Instead of hunting for scattered, low-quality YouTube links, consider these official platforms. They offer all 442 episodes in HD, uninterrupted, with subtitles. In the past, some episodes were released on
